Inside Cover: Vibrational Circular Dichroism Spectroscopy of Three Multidentate Nitrogen Donor Ligands: Conformational Flexibility and Solvent Effects (Chem. Asian J. 6/2013)
نویسندگان
چکیده
منابع مشابه
Conformational flexibility of Corey lactone derivatives indicated by absorption and vibrational circular dichroism spectra.
Infrared absorption and vibrational circular dichroism (VCD) spectra of four Corey lactone derivatives (diol, benzoate, p-phenylbenzoate, and bisbenzoate) were measured and analyzed on the basis of ab initio computations. The analysis interpreted most of the spectral features as well as the differences among individual compounds. Despite the common rigid lactone residue, conformational behavior...
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The three-dimensional structure of a peptide is strongly influenced by its solvent environment. In the present study, we study three cyclic tetrapeptides which serve as model peptides for β-turns. They are of the general structure cyclo(Boc-Cys-Pro-X-Cys-OMe) with the amino acid X being either glycine (1), or L- or D-leucine (L- or D-2). Using vibrational circular dichroism (VCD) spectroscopy, ...
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ژورنال
عنوان ژورنال: Chemistry - An Asian Journal
سال: 2013
ISSN: 1861-4728
DOI: 10.1002/asia.201390017